FMC CORP AGRICULTURAL CHEMICAL DIV -- PHOSPHORIC ACID (70-85%) -- 6810-01-244-7686
===================== Product Identification ===================== Product ID:PHOSPHORIC ACID (70-85%) MSDS Date:11/17/1997 FSC:6810 NIIN:01-244-7686 Status Code:A === Responsible Party === Company Name:FMC CORP AGRICULTURAL CHEMICAL DIV Address:1735 MARKET ST City:PHILADELPHIA State:PA ZIP:19103-3230 Country:US Info Phone Num:303-595-9048/800-321-1362 Emergency Phone Num:303-595-9048 Resp. Party Other MSDS Num.:7664-38-2 REV: 1 Chemtrec Ind/Phone:(800)424-9300 CAGE:91976 === Contractor Identification === Company Name:FMC CORP AGRICULTURAL CHEMICAL DIV Address:1735 MARKET ST Box:City:PHILADELPHIA State:PA ZIP:19103-3230 Country:US Phone:303-595-9048/800-321-1362 CAGE:91976 Company Name:HCI CHEMICALS (USA) INC City:HOUSTON State:TX Country:US Phone:713-880-4810 CAGE:TO549 Company Name:INDUSTRIAL CHEMICALS INC Address:2540 BELLWOOD RD Box:34365 City:RICHMOND State:VA ZIP:23234 Country:US Phone:804-275-9292 CAGE:8K073 Company Name:LOS ANGELES CHEMICAL CO Address:4545 ARDINE ST Box:1987 City:SOUTH GATE State:CA ZIP:90280 Country:US Phone:213-562-9500 Contract Num:SP0450-99-M-C408 CAGE:75656 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Minumum % Wt:70. Maxumum % Wt:85. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 = 3500 MG/KG (80% ) Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CAUSES SENSORY IRRITATION; CONTACT OF THE TISSUES WITH PHOSPHORIC ACID ALSO CAUSES CORROSIVE BURNS. MIST PRODUCES IRRITATION TO EYES, NOSE, THROAT AND LUNGS. CHRONIC: NO DATA AVAILABLE FOR THE PRODUCT . Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:PHOSPHORIC ACID, 70-85% AQUEOUS SOLUTIONS, IS EXPECTED TO HAVE LOW ORAL AND DERMAL TOXICITY. INHALATION OF MIST MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. THIS PRODUCT IS EXPECTED TO BE CORROSIVE TO THE EYES(MAY CAUSE BLINDNESS), AND 85% SOLUTIONS ARE EXPECTED TO BE CORROSIVE TO THE SKIN. INGESTION IS LIKELY TO CAUSE BURNS OF THE GASTRIONTESTINAL TRACT AND MAY BE EXACERBATED BY PRE-EXISTING SK IN OR RESPIRATORY CONDITIONS. Medical Cond Aggravated by Exposure: MAY BE EXACERBATED BY PRE-EXISTING SKIN OR RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER EYELID INTERMITTENTLY. SEE A MEDICAL DOCTOR OR OPHTHALOMOLOGIST IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER WHILE REMOVING CONTAMINATED CLOTHING AND/OR SHOES, AND THOROUGHLY WASH WITH SOAP AND WATER. OBTAIN IMMEDIATE MEDICAL ATTENTION. CONTACT A MEDICAL DOCTOR IF NECESSARY. INGESTION: RINSE MOUTH WITH WATER. DILUTE BY GIVING 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEE A MEDICAL DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL. EXTINGUISH FIRE USING AGENTS SUITABLE FOR NEARBY FIRES. Fire Fighting Procedures:NON-COMBUSTIBLE. EVOLVES HYDROGEN ON CONTACT WITH MOST METALS. ================== Accidental Release Measures ================== Spill Release Procedures:APPROACH RELEASE FROM UPWIND. STOP OR CONTROL LEAK USING SPECIAL PROTECTIVE CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. CONTROL RUN OFF AND ISOLATE DISCHARGED MATERIAL FOR PROPE R DISPOSAL. Neutralizing Agent:SODA ASH AND LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A WELL-VENTILATED , DRY AREA AWAY FROM ALKALIES AND MOST METALS. DO NOT STORE IN DIRECT SUNLIGHT. STORE ABOVE FREEZING. CONTACT WITH REACTIVE METALS (IE MILD STEEL, ALUMINUM) MAY GENERATE HYD ROGEN THAT MAY FORM AN EXPLOSIVE MIXTURE IN STORAGE VESSELS. Other Precautions:TRANSFER PRODUCT TO PROCESS IN HERMETICALLY CLOSED SYSTEM OR USE LOCAL EXHAUST. PURGE ALL LINES WITH NITROGEN BEFORE DISCONNECT. EMPTY DRUM AS THOROUGHLY AS POSSIBLE TO FACILITATE DISPOSAL. ALL PERSON NEL SHOULD WEAR CHEMICAL GOGGLES & RUBBER OR NEOPRENE GLOVES. DO NOT USE STEEL, ALUMINUM OR STAINLES S #304 LINES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED ACID/GAS CARTRIDGE OR CANISTER WITH FULL FACEPIECE UNLESS BREAK-THROUGH OCCURS, THEN USE AIRLINE SUPPLIED OR SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. Ventilation:PROVIDE MECHANICAL LOCAL EXHAUST VENTILATION TO PREVENT RELEASE OF MIST INTO THE WORK AREA. IF RELEASE IS EXPECTED USE RESPORATORY PROTECTION. Protective Gloves:RUBBER OR NEIPRENE. Eye Protection:USE CUP TYPE CHEMICAL GOGGLES. FULL FACE SHIELD MAY BE USED. Other Protective Equipment:RUBBER OR NEOPRENE APRONS OR FULL PROTECTIVE CLOTHING DEPENDING ON DEGREE OF EXPOSURE. RUBBER OR NEOPRENE FOOTWEAR. Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY. Supplemental Safety and Health NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:>130.C, 266.F B.P. Text:130-158C Melt/Freeze Pt:>-17.7C, .1F M.P/F.P Text:(75%0 -32C 985%) Vapor Pres:8-2 MMHG @ 25C Spec Gravity:1.5 - 1.7 pH:1.5 Evaporation Rate & Reference:NON-VOLATILE Solubility in Water:INFINITE Appearance and Odor:CLEAR LIQUID, NO ODOR Percent Volatiles by Volume:NON-VOLATILE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MILD STEEL AND ALUMINUM MAY REACT TO PRODUCE HYDROGEN GAS THAT CAN PRODUCE AND EXPLOSION IN CONFINED VESSELS. Stability Condition to Avoid:CONTACT WITH ALKALINE MATERIALS, AND REACTIVE METALS. Hazardous Decomposition Products:OXIDES OF PHOSPHORUS. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:EYE EFFECTS: CORROSIVE, RABBIT. SKIN EFFECTS: NON-CORROSIVE (75%, 80%) 4-HR RABBIT; CORRROSIVE (85%) 4-HR RABBIT. DERMAL LD50: (75 & 80%) LD50 >3160 MG/KG (RAT); LD50: (85%) >1260 MG/KG (RAT). ORAL LD 50: 75% = 4400 MG/KG; 80%=4200 MG/KG; 85%=3500 MG/KG (RAT). INHALATION LC50: NO DATA AVAILABLE FOR THE PRODUCT. TARGET ORGANS: EYES, SKIN, NOSE, THROAT, LUNGS. ===================== Ecological Information ===================== Ecological:ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE FOR THE PRODUCT. CHEMICAL FATE INFORMATION: INORGANIC COMPOUNDS IN CONTACT WITH THE SOIL, SUB-SURFACE OR SURFACE WATERS MAY BE TAKEN UP BY PLANTS AND U TILIZED AS ESSENTIAL NUTRIENTS. PHJOSPHATES MAY ALSO FORM PRECIPITATES, USUALLY WITH CALCIUM OR MAGNESIUM. THE RESULTANT COMPOUNDS ARE INSOLUBLE IN WATER AND MAY BECOME PART OF THE SOIL OR SEDIMENT. T HE TERM BIODEGRADABILITY, AS SUCH, IS NOT APPLICABLE TO INORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF PHOSPHORIC ACID IS TO BE USED IN WATER REACTIONS, TRIPLE RINSE DRUM WITH WATER AND PUT INTO PROCESS (REDUCE WATER VOLUME EQUAL TO RINSING). SODA ASH AND LIME MAY BE USED AS NEUTRALIZING AGENTS FOR MATERIAL THAT CANNOT BE SALVAGED. NEUTRALIZED LIQUID MAY BE DISCHARGED TO TREATMENT IN ACCOREDANCE W ITH REGULATORY PROCEDURES. =================== MSDS Transport Information =================== Transport Information:US DOT: PROPER SHIPPING NAME: PHOSPHORIC ACID. PRIMARY HAZARD CLASS: 8 9CORROSIVE). UN/NA NUMBER: UN 1805. PACARDS: CORROSIVE. LABEL: CORROSIVE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311 HAZARD CATEGORY (40 CFR 370): IMMEDIATE (ACUTE) HEALTH HAZARD. SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): 10,000 LBS. SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): LISTED. SE CTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NOT LISTED, RQ=5000 LBS. Federal Regulatory Information:CERCLA REGULATORY (40 CFR 302.4): PHOSPHORIC ACID (UNLISTED): RQ=100 LBS, CORROSIVITY. CERCLA RQ: LISTED RQ=5000 LBS. CATEGORY: D. TSCA STATUS (40 CFR 710): ;ISTED. RCRA STATUS: WASTE NUMBER D002. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.