SPECTRUM CHEMICAL MANUFACTURING CORP. -- SODIUM BISULFITE -- 6810-00-241-1096
===================== Product Identification ===================== Product ID:SODIUM BISULFITE MSDS Date:02/02/1989 FSC:6810 NIIN:00-241-1096 === Responsible Party === Company Name:SPECTRUM CHEMICAL MANUFACTURING CORP. Address:14422 SOUTH SAN PEDRO STREET City:GARDENA State:CA ZIP:90248-2027 Country:US Info Phone Num:213-516-8000 Emergency Phone Num:213-516-8000 CAGE:63415 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BISULFITE (SASA III) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 100% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT)= 2000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CHRONIC: INHALE:REPEATED OR PROGONGED EXPOSURE MAY CAUSE SENSITIZATION; SKIN:MAY CAUSE DERMATITIS SENSITIZATION; EYE: MAY CAUSE CONJUNCTIVITIS; INGEST:MAY CAUSE SENSITIZATION. ACUTE: SEE OVEREXPOSURE SYMPTOMS. Explanation of Carcinogenicity:NOT LISTED UNDER NTP, IARC, OR OSHA. Effects of Overexposure:INHALE: ITTITATION WITH SORE THROAT, COUGHING, & SHORTNESS OF BREATH. AQUEOUS SOLUTIONS MAY CAUSE SEVERE IRRITATION; SKIN: IRRITATION, AQUEOUS SOLUTIONS MAY CAUSE SEVERE IRRITATION WITH POSSIBLE CORPO SION; EYE: IRRITATION, AQUWEOUS SOLUTION MAY CAUSE SEVERE IRRITAION WITH POSSIBLE CORROSION; INGEST: IRRITATION OF STOMA Medical Cond Aggravated by Exposure:CH, WITH ABDOMINAL PAIN & NAUSEA. FOR SUSCEPTIBLE INDIVIDUALS, IT MAY CAUSE GENERALIZED FLUSHING, FAINTNESS, BRONCHOSPASMS WITH WHEEZING & SHORTNESS OF BREATH, ANGIOEDEMA, HIVES, ITCHING, ETC. ======================= First Aid Measures ======================= First Aid:INHALE: REMOVE FROM EXPOSURE AREA TO FRESH AIR, IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION, KEEP WARM & AT REST; SKIN/EYE: WASH AFFECTED AREA WITH LOTS OF WATER, REMOVE CONTAMINATED CLOT HING & SHOES; INGEST: DO NOT USE GASTPIC LAVAGE OR ENESIS. DULUTE THE ACID IMMEDIATELY BY DRINKING LARGE QUANTITIES OF WATER OR MILK. IF VOMITING PERSISTS, ADMINISTER FLUIDS REPEATEDLY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE STATED. ================== Accidental Release Measures ================== Spill Release Procedures:DIG A PIT, POND, LAGOON R HOLDING AREA TO CONTAIN LIQUID OR SOLID MATERIAL, COVER SOLIDS WITH A PLASTIC SHEET TO PREVENT DISSOLVING IN RAIN OR FIREFIGHTING WATER. Neutralizing Agent:CAUSTIC SODA ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCIMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, USE A RESPIRATOR APPROVED BY NIOSH/MSHA, SUCH AS AIR-PURIFYING FULL FACEPIECE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESSURE DEMAND MODE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND GENERAL DILUTION VENTILATION TO BRING BELOW TLV. Protective Gloves:RUBBER GLOVES Eye Protection:SPLASH-PROOF OR DUST RESISTANT GOGGLES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Spec Gravity:1.4 pH:<7 Solubility in Water:SOLUBLE Appearance and Odor:WHITE CRYSTAL OR CRYSTALLINE POWDER WITH A SLIGHT SULFUROUS ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH ALUMINUM, STRONG ACIDS & OXIDIZERS. Hazardous Decomposition Products:TOXIC OXIDES OF SULFUR & TOXIC SODIUM OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH FEDERAL,STATE & LOCAL REGULATIONS Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.