FISHER SCIENTIFIC -- TOLUENE -- 6685-00-888-0157
===================== Product Identification ===================== Product ID:TOLUENE MSDS Date:04/29/1998 FSC:6685 NIIN:00-888-0157 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:(800)424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 Company Name:LUCENT TECHNOLOGIES INC NETWORK SYSTEMS Address:I-85 AND MT HOPE CHURCH RD Box:City:MC LEANSVILLE State:NC ZIP:27301 Country:US Phone:336-279-4964 Contract Num:SP0440-99-M-QC57 CAGE:07YF9 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, METHYL- CAS:108-88-3 RTECS #:XS5250000 > Wt:99. OSHA PEL:see Table Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 636 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE-CAUSES EYE IRRITATION. MAY RESULT IN CORNEAL INJURY. VAPORS MAY CAUSE EYE IRRITATION. SKIN-MAY CAUSE SKIN IRRITATION. PROLONGED &/OR REPEATED CONTACT MAY CAUSE IRRITATION */OR DERMATITIS. INGESTI ON-ASPIRATION HAZARD. MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE EFFECTS SIMILIAR TO THOSE FOR INHALATION EXPOSURE. ASPIRATION OF MATERIAL INTO THE LUNGS MAY CAUSE CHEMICAL PNEUMONITIS, WH ICH MAY BE FATAL. INHALATION-MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. CHRONIC:PROLONGED OR REPEATED CONTACT MAY CAUSE DERMATITIS. MAY CAUSE CARDIAC SENSITIZATION & SEVERE HEART ABNORMALITIES. MAY CAU SE LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:ACGIH: 4A - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. IARC: GROUP 3 CARCINOGEN. Effects of Overexposure:INHALATION-HEADACHE, DIZZINESS, UNCONSCIOUSNESS AND COMA. INHALATION OF VAPOR MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE LIVER AND KIDNEY DAMAGE. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. OVER EXPOSURE MAY CAUSE DIZZINESS, TREMORS, RESTLESSNESS, RAPID HEART BEAT, INCREASED BLOOD PRESSURE, HULLUCINATION, ACIDOSIS, KIDNEY FAILURE. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH EYES WITH PLENTY OF WATER FOR 15 MIN, OCCASIONALLY LIFTING THE UPPER & LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN-FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 MIN WHILE REMOVING CONTA MINATED CLOTHING & SHOES. GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. INGESTION-DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING B Y MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID IMMEDIATELY. INHALATION-GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. ===================== Fire Fighting Measures ===================== Flash Point:=4.4C, 40.F Autoignition Temp:=480.C, 896.F Lower Limits:1.1 Upper Limits:7.1 Extinguishing Media:USE WATER TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. DO NOT USE STRAIGHT STREAMS OF WATER. USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. Fire Fighting Procedures:CONTAINERS CAN BUILD UP PRESSURE IS EXPOSED TO HEAT/FIRE. WEAR A SELF-CONTAINED BREATHING APPRATUS IN PRESSURE-DEMAND, MSHA/NIOSH, & FULL PROTECITVE GEAR. DIKE & COLLECT WATER USED TO FIGHT FIRE. FLAM MABLE LIQUID. FOR LARGE FIRES, USE WATERSPRAY, FOG, OR REGULAR FOAM. Unusual Fire/Explosion Hazard:VAPORS MAY FORM AN EXPLOSIVE MIXTURE WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. DO NOT USE STRAIGHT STRE AMS OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID RUNOFF INTO STORM SEWERS & DITCHES WHICH LEAD TO WATERWAYS. REMOVE ALLS OURCES OF IGNITION. ABSORB SPILL USING AN ABSORBENT, NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SNAD, OR VERMICULITE. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCEVAPORS. WATER SPRAY MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND FLAME. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP CONT AINER TIGHTLY CLOSED. Other Precautions:GROUND & BOND CONTAINERS WHEN TRANSFERRING MATERIAL. EMPTY CONTAINERS RETAIN PRODUCT RESIDUES & CAN BE DANGEROUS. AVOID HEAT, SPARKS AND FLAMES. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GR IND, OR EXPOSE EMPTY CONTAINERS TO HEAT,SPARKS OR OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT SKIN EXPOSURE. Eye Protection:EYEGLASSES OR CHEMICAL SAFETY GOGGLES. Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Supplemental Safety and Health NOTES TO PHYSICIAN: CAUSES CARDIAC SENSITIZATION TO ENDODOGENOUS CATELCHOLAMINES WHICH MAY LEAD TO CARDIAC ARRHYTHMIAS. DO NOT USE ADRENERGIC AGENTS SUCH AS EPINEPHRINE OR PSEUDOEPINEPHRINE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=111.1C, 232.F Melt/Freeze Pt:=-95.C, -139.F Vapor Pres:36.7 MM HG @ 30C Vapor Density:3.1 Viscosity:0.59 CP @ 20C Evaporation Rate & Reference:2.4 (BUTYL ACETATE=1) Solubility in Water:0.6 MG/L H2O AT 68F Appearance and Odor:COLOURLESS LIQUID, PLEASANT SWEETISH ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NTROGEN TETROXIDE, NITRIC ACID + SULFURIC ACID, SILVER PERCHLORATE, STRONG OXIDIZERS, SODIUM DILFUORIDE. Stability Condition to Avoid:IGNITION SOURCES, EXCESS HEAT Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information =================== Toxicological Information:CAS# 108-88-3; INHALATION, MOUSE: LC50=400 PPM/24HR; INHALATION, RAT: LC50=49 GM/M3/4H; ORAL, RAT: LD50=636 MG/KG; SKIN, RABBIT: LD50=12124 MG/KG. TETRATOGENICITY: SPECIFIC DEVELOPMENTAL ABNORMALITIES INCLUDED CRANIOFACIAL EFFECTS INVOLVING THE NOSE & TONGUE, MUSCULOSKELETAL EFFECTS, UROGENITAL & METABOLIC EFFECTS IN STUDIES ON MICE & RATS BY INHALATION & ORAL ROUTES OF EXPOSURE. SOME EVIDENCE OF FETOTOXICITY WITH REDUCED FETAL WEIGHT & RETARDED SKELETAL DEVELOPMENT HAS BEEN REPORTED IN MICE & RATS. REPRODUCTIVE EFFECTS: EFFECTS ON FERTILITY SUCH AS ABORTION& PATERNAL WERE REPORTED IN RABBITS BY INHALATION. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: BLUEGILL LC50=17 MG/L/24H SHRIMP LC50=4.3 PPM/96H FATHEAD MINNOW LC50=36.2 MG/L/96H SUNFISH (FRESH WATER) TLM=1180 MG/L/96H. ENVIRONMENTAL FATE: FROM SOIL, SUBSTANCE VOLATILIZES AND IS MI CROBIALLY BIODEGRADED. IN WATER, SUBSTANCE VOLATILIZES AND BIODEGRADES. PHYSICAL/CHEMICAL: PHOTOCHEMICALLY PRODUCED HYDROXYL RADICALS DEGRADE SUBSTANCE. OTHER: NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: CAS# 108-88-3: WASTE NUMBER U220. CAS# 108-88-3 IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: TOLUENE. HAZARD CLASS: 3. UN NUMBER: UN1294. PACKING GROUP: II. CANADIAN TDG: SHIPPING NAME: TOLUENE. HAZARD CLASS: 3(9.2). UN NUMBER: UN1294. OTHER INFORMATION: FLASHPOINT 4C. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302(RQ) CAS# 108-88-3: FINAL RQ=1000 POUNDS (454 KG). SECTION 302(TPQ) NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES CAS# 108-88-3: ACUTE, FLAMMABLE. SECTION 313: THIS MATERIAL CONTAINS BENZENE, METHYL- (CAS# 108-88-3, 99%), WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR PART 373. Federal Regulatory Information:TSCA: CAS# 108-88-3 IS LISTED ON THE TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST, CAS# 108-88-3: EFFECTIVE DATE: OCTOBER 4, 1982; SUNSET DATE: OCTOBER 4, 1992. CHEMICAL TEST RULES: NONE OF THE CHEM ICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE. NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION 12B. NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. State Regulatory Information:CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. WARNING: THIS PRODUCT CONTAINS BENZENE, METHYL-, A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER RE PRODUCTIVE HARM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.