MALLINKRODT-BAKER (FORMALLY J.T. BAKER COMPANY) -- HYDROCHLORIC ACID,37% -- 6810-00-753-4786
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID,37% MSDS Date:12/08/1995 FSC:6810 NIIN:00-753-4786 === Responsible Party === Company Name:MALLINKRODT-BAKER (FORMALLY J.T. BAKER COMPANY) Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:800-582-2537 EXT 6501 Emergency Phone Num:908-859-2151/800-424-9300(CHEMTREC) CAGE:EO303 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 Company Name:MALLINKRODT-BAKER (FORMALLY J.T. BAKER COMPANY) Address:222 RED SCHOOL LANE Box:NONE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Phone:800-582-2537 EXT 6501/908-859-2151 CAGE:EO303 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 37% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 63% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 (INHALATION, RAT): 3124 PPM/1 H Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, TEETH, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE & TOXIC. INHALE:MAY CAUSE INFLAMMATION, CHOCKING, COUGHING, LUNG DAMAGE. EYE/SKIN:SEVERE BURNS. MAY CAUSE PERMANENT EYE DAMAG E. ORAL:IMMEDIATE PAIN & BURNS OF MOUTH, THROAT, ESOPHAGUS & GI TRACT. MAY BE FATAL. CHRONIC- TEETH EROSION, DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, BURNS, COUGHING, DIFFICULT BREATHING, CHEST PAIN, ABDOMINAL PAIN, NAUSEA, VOMITING, DENTAL EROSION, CHOCKING, SKIN REDNESS OR DISCOLORATION, DEEP ULCERATION, EYE DAMAGE, CIRCULATORY COLLAPSE, DEATH Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL HELP FOR ALL CASES OF EXPOSURE. EYES/SKIN:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL:DO NOT I NDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE. REACTS WITH MOST METALS FORMING HYDROGEN WHICH CAN EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE AREA. REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). DO NOT RELEASE INTO SOIL, SEWER. NEUTRALIZE WITH SODA ASH/SODIUM BICARBONATE. USE AN ABSORBENT SUCH AS SA ND/VERMICULITE ON SLURRY. TRANSFER TO CONTAINER. Neutralizing Agent:SODA ASH, LIME, SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED, CORROSION-PROOF AREA, AWAY FROM DIRECT SUNLIGHT, FLAME AND INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DANGER! STRONG ACID. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID BREATHING VAPORS/MIST. USE UNDER THE HOOD WITH ADEQUATE VENTILATION. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. WASH THOROUGHLY AFTER HANDLING. DO NOT INGEST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED RESPIRATOR WITH AN ACID CARTRIDGE. IN EMERGENCY, WEAR A NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR. USE LAB HOOD. Ventilation:PROVIDE GENERAL VENTILATION OR LOCAL EXHAUST TO MEET OSHA PERMISSIBLE EXPOSURE LIMITS (OSHA PEL). Protective Gloves:PVC, NEOPRENE Eye Protection:CHEMICAL SAFETY GOGGLES AND FACE SHIELD Other Protective Equipment:USE RUBBER SPLASH APRON AND RUBBER BOOTS. EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PERCENTAGE CHANGED. FOR PREVIOUS CONCENTRATION, SEE PNI A, SAME NSN. NOTE TO PHYSICIAN:WASH AFFECTED SKIN AREAS WITH A 5% SOLUTION OF SODIUM BICARBONATE. IF INGESTED, THE RISK VERSUS THE BENEFIT OF TH E PASSAGE OF A NASO-GASTRIC TUBE IS DEBATABLE. DO NOT GIVE THE EXPOSED PERSON BICARBONATE TO NEUTRALIZE THE MATERIAL. ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:127F,53C Melt/Freeze Pt:M.P/F.P Text:-101F,-74C Vapor Pres:190 @ 77F Vapor Density:1.26 Spec Gravity:1.18 pH:<2 Solubility in Water:INFINITE Appearance and Odor:CLEAR, COLORLESS FUMING LIQUID - SHARP, PUNGENT, IRRITATING ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES, METALS, METAL OXIDES, HYDROXIDES, AMINES, CARBONATES, CYANIDES, SULFIDES, SULFITES, FORMALDEHYDE Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:MAY EMIT HYDROGEN CHLORIDE VAPORS OR GAS, CHLORINE, OXIDES OF CHLORINE, HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATORS FOR PROPER DISPOSAL. CONSIDER RECYCLING. REPORTABLE QUANTITY (RQ), CERCLA: 5000 LBS. 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