QUANTUM CHEMICAL CORP -- DENATURED ALCOHOL -- 6810-00-201-0906
===================== Product Identification ===================== Product ID:DENATURED ALCOHOL MSDS Date:03/28/1991 FSC:6810 NIIN:00-201-0906 === Responsible Party === Company Name:QUANTUM CHEMICAL CORP Address:11500 NORTHLAKE DR Box:429550 City:CINCINNATI State:OH ZIP:45249-1642 Country:US Info Phone Num:513-530-6500 Emergency Phone Num:513-530-6500 Preparer's Name:C.A. EISENHARD CAGE:78918 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:QUANTUM CHEMICAL CORPORATION USI DIVISION Address:11500 NORTHLAKE DRIVE Box:429550 City:CINCINNATI State:OH ZIP:45249 Country:US Phone:713-479-2873/800-424-9300(CHEMTREC) CAGE:78918 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 95.2% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 4.8% Other REC Limits:NONE SPECIFIED OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Other REC Limits:NONE SPECIFIED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-FOR PURE ETHANOL.INHALATION:EXPOSURE TO OVER 1000 PPM MAY CAUSE HEADACHE,DROWSINESS & IRRITATION OF THROAT.INGESTION:CAN CAUSE DEPRESSION OF CNS,NAUSEA,VOMITING,DIARRHEA.METHANOL MAY CAUSE BLIND NESS OR DEATH.EYE:MAY CAUSE IRRITATION.SKIN:PROLONGED CONTACT MAY CAUSE IRRITATION & DEFATTING.CHRONIC-NOT GIVEN. Explanation of Carcinogenicity:BENZENE (CARCINOGEN/BLOOD). Effects of Overexposure:SEE HEALTH HAZARDS SECTION. Medical Cond Aggravated by Exposure:NOT GIVEN. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IN ALL CASES.SWALLOWED:IF CONSCIOUS,DRINK WATER/MILK TO DILUTE.INDUCE VOMITING IF ADVISED BY PHYSICIAN/POISON CONTROL CENTER.INHALED:IMMEDIATELY REMOVE TO FRESH AIR.GIVE CPR IF N ECESSARY.EYES/SKIN:FLUSH WITH PLENTY OFCOOL WATER.FLUSH EYE FOR AT LEAST 15 MINUTES.REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:60.0F,15.6C Lower Limits:3.3 Upper Limits:19 Extinguishing Media:USE CARBON DIOXIDE, ALCOHOL-TYPE FOAM, OR DRY CHEMICAL. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS IN THE POSITIVE PRESSURE MODE WITH A FULL FACEPIECE.USE WATER SPRAY TO COOL CONTAINERS OR DISPERSE THE VAPORS. Unusual Fire/Explosion Hazard:SMOKE, FUMES AND HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION.WEAR APPROPRIATE RESPIRATORY PROTECTION AND PROTECTIVE CLOTHING.CONTAIN SPILLED MATERIAL.TRANSFER TO SECURE CONTAINERS.WHERE NECESSARY,COLLECT USING ABSORBENT MEDIA.T HE USER SHOULD DETERMINE IF SPILL IS REPORTABLE. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORING OUTSIDE IS PREFERRED.INSIDE STORAGE SHOULD BE IN A NFPA APPROVED FLAMMABLE LIQUIDS STORAGE ROOM/CABINET. Other Precautions:FOR INDUSTRIAL USE ONLY.CONTAINS 4.8% METHANOL.ISOLATE FROM OXIDIZERS,HEAT,SOURCES OF IGNITION & EXPLOSIVE.BOND & GROUND CONTAINERS WHEN TRANSFERRING LIQUID.NEVER USE PRESSURE TO EMPTY.CONTAINERS HAZA RDOUS WHEN EMPTY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE NIOSH-APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR ORGANIC VAPOR IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE. Ventilation:LOCAL EXHAUST AS NECESSARY TO MEET TWA LIMITS. Protective Gloves:NEOPRENE, NITRILE, PVC OR NATURAL RUBBER Eye Protection:SAFETY GLASSES OR SPLASH-PROOF GOGGLES Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health POISON - DANGER! CONTAINS METHANOL; MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:173F,78C Vapor Pres:44.6 Vapor Density:1.59 Spec Gravity:0.794 Solubility in Water:COMPLETE Appearance and Odor:CLEAR AND COLORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND ACETYL CHLORIDE Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKED, LABELED, TRANSPORTED AND DISPOSED OR RECLAIMED IN CONFORMANCE WITH APPLICABLE LAWS AND REGULATIONS AND IN CONFORMANCE WITH GOOD ENGINEERING PRACTICES. 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