TRI-GAS, INC -- HELIUM -- 6830-00-169-0789
===================== Product Identification ===================== Product ID:HELIUM MSDS Date:10/01/1985 FSC:6830 NIIN:00-169-0789 === Responsible Party === Company Name:TRI-GAS, INC Address:4545 FULLER DRIVE, SUITE 100 City:IRVING State:TX ZIP:75038 Country:US Info Phone Num:214-650-1700 Emergency Phone Num:800-442-7412 CAGE:TRIGA === Contractor Identification === Company Name:TRI-GAS, INC Address:4545 FULLER DRIVE, SUITE 100 Box:City:IRVING State:TX ZIP:75038 Country:US Phone:214-650-1700 CAGE:TRIGA ============= Composition/Information on Ingredients ============= Ingred Name:HELIUM CAS:7440-59-7 RTECS #:MH6520000 Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9394 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HELIUM:SIMPLE ASPHYXIANT.EFFECTS OF EXPO TO HIGH CONC SO AS TO DISPLACE OXY IN AIR NECESASRY FOR LIFE:HEAD,DIZZ,LABORED BREATHING & EVENTUAL UNCONSC.BREATHING MIXTURES OF HELIUM W/ADEQUATE OXY TO SUPP ORT LIFE MODIFIES VOICE SOUND AS THAT IT IS HIGHER "PITCHED".NON-TOXIC BUT LG AMTS IN CONFINED AREA CAN DISPLACES OXYGEN Explanation of Carcinogenicity:PER MSDS:LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN:NTP/IARC/OSHA:NO. Effects of Overexposure:HEADACHE, DIZZINESS, LABORED BREATHING, EVENTUAL UNSCONSCIOUSNESS. MODIFIES VOICE SOUND SO THAT IT IS HIGHER "PITCHED". Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:PROMPT MED ATTN MANDATORY IN ALL CASES OF OVEREXPO TO HELIUM.RESCUE PERSONNEL SHOULD BE EQUIPPED W/SCBA.INHAL:CONSC PERSONS SHOULD BE ASSISTED TO UNCONTAMIN AREA.INHAL FRESH AIR.QUICK REMOVAL FROM CON TAMIN AREA IS MOST IMPORTANT.UNSCONSC PERSONS SHOULD BE MOVED TO UNCONTAMIN AREA GIVEN MOUTH-TO-MOUTH RESUSCITATION & SUPPLEMENTAL OXY.MED ASSISTANCE SHOULD BE SOUGHT IMMED. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE GAS, INERT GAS. HOWEVER USE APPROPRIATE EXTINGUISHING MEDIA FOR SURROUNDING FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE, CONTACT THE CLOSEST TRI-GAS INC LOCATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VENTI AREA.VAL PROT CAPS MUST REMIAN IN PLACE UNLESS CNTNR SECURED W/VAL OUTLET PIPED TO USE PT.DO NOT DRAG/SLIDE/ROLL CYL;USE HANDTK Other Precautions:STORE UPRIGHT/FIRMLY SECURED.SEGRAGATE EMPTY/FULL.USE PRESS REDUCING REG WHEN CONNECTING CYL TO LOWER PRESS PIPING TO SYS.KEEP OXY LEVELS @<18 MOLAR% @NORMAL ATM PRESSURE WHICH IS EQUIVALENT TO PARTIA L PRESSURE OF 135MM HG(ACGIH 1984-86). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH MASK OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE. Ventilation:LOCAL EXHAUST:TO PREVENT ACCUMULATION OF HIGH CONCENTRATIONS SO AS TO REDUCE OXYGEN LEVEL IN AIR TO LESS THAN 18MOLAR %. Protective Gloves:ANY MATERIAL Eye Protection:SAFETY GGOLES OR GLASSES Other Protective Equipment:SAFETY SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health LIQ DEN @BPT:7.801LB/FT3(124.96KG.M3).PRECAUTIONS:DO NOT HEAT CYL SO TO INCREASE DISCHARGE RATE OF MATL FRM CYL.USE CHECK VALV/TRAP IN DISCHARGE LINE TO PREVENT HAZ BACKFLOW INTO CYL.PROTECT FRM PHYSI CAL DAMAGE.STORE IN COOL DRY WELL VENTILATED AREA AWAY FROM HEAVILY TRAFFICKED AREA/EMERGENCY EXITS. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-452F,-269C Melt/Freeze Pt:M.P/F.P Text:-456F,-271C Vapor Pres:<-450F Vapor Density:0.0104@59F Spec Gravity:0.14 @70F Solubility in Water:0.0086,BUNSEN COEFF Appearance and Odor:COLORLESS, ODORLESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. HELIUM IS NON-CORROSIVE & MAY BE USED WITH ANY COMMON STRUCTURAL MATERIAL. Stability Condition to Avoid:DO NOT ALLOW TEMP WHERE CYL ARE STORED TO EXCEED 130F(54C). Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE/UNUSED QUANT.RETURN IN SHIPPING CNTNR PROPERLY LABEL W/ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROT CAP IN PLACE TO TRI-GAS FOR PROPER DISPOSAL.EMERGENCY DISPOSA L CONTACT TRI-GAS.DO NOT REFILLED CYL-VIO FED LAW. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.